Temperature-responsive polymers : chemistry, properties and applications / English.
ed by Vitaliy V. Khutoryanskiy, and Theoni K. Georgiou.
- 1st ed.
- Hoboken, NJ : Wiley, 2018.
- xxii, 384 p. illustrations ; 25 cm
Includes bibliographical references and index.
Chemistry Poly(N-isopropylacrylamide): Physicochemical Properties and Biomedical Applications PNIPAM as Thermosensitive Polymer Physical Properties of PNIPAM Phase Behavior of PNIPAM in Water/Alcohol Mixtures Effect of Concentration and Molecular Weight of PNIPAM on LCST Effect of Surfactants on LCST Effect of Salts on LCST Common Methods for Polymerization of NIPAM Free Radical Polymerization Living Radical Polymerization ATRP of NIPAM RAFT Polymerization of NIPAM Dual Sensitive Systems pH and Thermosensitive Systems Reduction-Sensitive and Thermosensitive Systems Hybrid-Thermosensitive Materials Bioconjugation of PNIPAM Protein-PNIPAIVI Conjugates Peptide-PNIPAM Conjugates Nucleic Acid-PNIPAM Conjugates Liposome Surface Modification with PNIPAM Applications of PNIPAM in Cell Culture Crosslinking Methods for Polymers Crosslinking in PNIPAM-Based Hydrogels Crosslinking of PNIPAM-Based Micelles Shell Crosslinked (SCL) Core Crosslinked (CCL) Conclusion and Outlook of Applications of PNIPAM Thermoresponsive Multiblock Copolymers: Chemistry, Properties and Applications Chemistry of Thermoresponsive Block-based Copolymers Architecture, Number of Blocks and Block Sequence Why the Block Structure? Triblock Copolymers Micelles Gels Films and Membranes Tetrablock Copolymers Pentablock Copolymers Pluronic® Based Non-pluronic Based Multiblock Copolymers Star-shaped Poly(2-alkyl-2-oxazolines): Synthesis and Properties Synthesis of Star-shaped Poly(2-alkyl-2-oxazolines) Properties of Star-shaped Poly(2-alkyl-2-oxazolines) Poly(N-vinylcaprolactarn): From Polymer Synthesis to Smart Self-assemblies Synthesis of PVCL Homo- and Copolymers Synthesis of Statistical PVCL Copolymers Synthesis of PVCL Block Copolymers Other PVCL-based Copolymers Properties of PVCL in Aqueous Solutions Dependence of the LCST of PVCL on Molecular Weight and Polymer Concentration LCST Dependence on Chemical Composition The Effect of Salt on the PVCL Temperature Response The Effect of Solvent on PVCL Temperature Response Assembly of PVCL-based Polymers in Solution PVCL Interpolymer Complexes PVCL-based Micelles Self-assembly of PVCL-based Copolymers into Polymersomes Templated Assemblies of PVCL Polymers Hydrogen-bonded PVCL-based Multilayers pH-sensitive Hydrogen-bonded PVCL Multilayers Enzymatically Sensitive Hydrogen-bonded PVCL Multilayers Multilayer Hydrogels of PVCL Outlook and Perspectives Sodium Alginate Grafted with Poly(N-isopropylacrylarnide) Alginic Acid Monomeric and Polymeric Structure of Alginates Poly(N-Isopropylacrylamide) and Thermoresponsive Properties Synthesis and Characterization of Alginate-graft-PNIPAM Copolymers Solution Properties Turbidimetry Fluorescence Rheology Degradability Biocompatibility Cytotoxicity Pharmaceutical and Medical Applications Multi-stimuli-responsive Polymers Based on Calix[4]arenes and Dibenzo-18-crown-6-ethers Single-stimuli-responsive Polymers Thermo-responsive Polymers in Polar Media pH-responsive Polymers Photoresponsive Polymers Other Single-stimuli-responsive Polymers Multi-stimuli-responsive Polymers Poly(azocalix[4]arene)s and Poly(azodibenzo-18-crown-6-ether)s Calixarenes Crown Ethers Structural Units of Poly(azocalix[4]arene)s Structural Units of Poly(azodibenzo-18-crown-6-ether)s Photoisomerization Host-guest Interactions Thermo-responsiveness LCST: Tegylated Poly(azocalix[4]arene)s in Water UCST: Tegylated Poly(azocalix[4]arene)s in Alcohols UCST and Photoisomerization of Tegylated Poly(azocalix[4]arene)s UCST and Poly(azodibenzo-18-crown-6-ether)s UCST and Photoisomerization of Poly(azodibenzo-18-crown-6-ether)s UCST in Water-alcohol Mixtures Solvatochromism and pH Sensitivity Characterization of Temperature-responsive Polymers Small-Angle X-ray and Neutron Scattering of Temperature-Responsive Polymers in Solutions Temperature-responsive Homopolymers Hydrophobically Modified Polymers Cross-Linked Temperature-Sensitive Polymers and Gels Temperature-Responsive Block Copolymers Hybrid Nanoparticles Gradient Temperature-Responsive Polymers Multi-responsive Copolymers Infrared and Raman Spectroscopy of Temperature-Responsive Polymers Experimental Methods to Measure IR and Raman Spectra of Aqueous Solutions Poly(N-substituted acrylarnide)s Overall Spectral Change Amide Bands C-H Stretching Bands C-D Stretching Band Poly(vinyl ether)s Poly(meth)acrylates Effects of Additives on Phase Behavior Temperature-Responsive Copolymers and Gels Application of NMR Spectroscopy to Study Thermoresponsive PolymersJirí Spęvácek Coil-Globule Phase Transition and Its Manifestation in NMR Spectra Temperature Dependences of High-Resolution NMR Spectra: Phase-Separated Fraction p Multicomponent Polymer Systems Effects of Low-Molecular-Weight Additives on Phase Transition Behavior of Water at the Phase Transition Polarized Luminescence Studies of Nanosecond Dynamics of Thermosensitive Polymers in Aqueous Solutions Theoretical Part Polarization of Luminescence The Use of Polarized Luminescence in the Studies of Nanosecond Dynamics of Macromolecules Experimental Part Methods of Synthesis of Polymers Containing Luminescent Markers Technique for Measurement of Luminescence Polarization Thermosensitive Water-Soluble Polymers pH and Thermosensitive Water-Soluble Polymers Temperature-Induced Transitions in Polymers in Nonaqueous Solutions Applications of Temperature-responsive Polymers Applications of Temperature-Responsive Polymers Grafted onto Solid Core Nanoparticles Silica Nanoparticles pNIPAM-functionalised Silica Nanoparticles Poloxamer-functionalised Silica Nanoparticles Other Polymers Metallic Nanoparticles pNIPAM-functionalised Metallic Nanoparticles Poloxamer-functionalised Metallic Nanoparticles Marzieh Najafi and Erik Hebels and Wim F. Hennink and Tina Vermanden -- Anna P. Constantinou and Theoni K. Georgiou -- Andrey V. Tenkovtsev and Alina I. Amirova and Alexander P. Filippov -- Fei Liu and Veronika Korlovskaya and Eugenia Kharlampieva -- Catalina N. Cheaburu-Yilmaz and Cornelia Vasile and Oana-Nicoleta Ciocoiu and Georgios Staikos -- Szymon Wiktorowicz and Heikki Tenhu and Vladimir Aseyev -- Sergey K. Filippov and Martin Hruby and Petr Stepanek -- Yasushi Maeda -- Vladimir D. Pautov and Tatiana N. Nekrasova and Tatiana D. Anan'eva and Ruslan Y. Smyslov -- Edward D.H. Mansfield and Adrian C. Williams and Vitaliy V. Khutoryanskiy -- Part I p. 1 -- 1 p. 3 / 1.2 p. 4 -- 1.3 p. 5 -- 1.3.1 p. 5 -- 1.3.2 p. 5 -- 1.3.3 p. 7 -- 1.3.4 p. 7 -- 1.4 p. 8 -- 1.4.1 p. 8 -- 1.4.2 p. 9 -- 1.4.2.1 p. 10 -- 1.4.2.2 p. 11 -- 1.5 p. 12 -- 1.5.1 p. 12 -- 1.5.2 p. 13 -- 1.5.3 p. 13 -- 1.6 p. 15 -- 1.6.1 p. 16 -- 1.6.2 p. 18 -- 1.6.3 p. 21 -- 1.7 p. 21 -- 1.8 p. 22 -- 1.9 p. 23 -- 1.9.1 p. 23 -- 1.9.2 p. 26 -- 1.9.2.1 p. 26 -- 1.9.2.2 p. 27 -- 1.10 p. 27 -- 2 p. 35 / 2.2 p. 35 -- 2.3 p. 38 -- 2.3.1 p. 38 -- 2.3.2 p. 39 -- 2.3.2.1 p. 40 -- 2.3.2.2 p. 45 -- 2.3.2.3 p. 52 -- 2.3.3 p. 53 -- 2.3.4 p. 54 -- 2.3.4.1 p. 54 -- 2.3.4.2 p. 56 -- 2.3.5 p. 57 -- 3 p. 67 / 3.2 p. 68 -- 3.3 p. 78 -- 4 p. 93 / 4.2 p. 93 -- 4.2.1 p. 95 -- 4.2.2 p. 97 -- 4.2.3 p. 99 -- 4.3 p. 99 -- 4.3.1 p. 99 -- 4.3.2 p. 100 -- 4.3.3 p. 102 -- 4.3.4 p. 102 -- 4.4 p. 102 -- 4.4.1 p. 102 -- 4.4.2 p. 103 -- 4.4.3 p. 105 -- 4.5 p. 107 -- 4.5.1 p. 107 -- 4.5.1.1 p. 107 -- 4.5.1.2 p. 108 -- 4.5.2 p. 110 -- 4.6 p. 113 -- 5 p. 121 / 5.1 p. 121 -- 5.1.1 p. 121 -- 5.2 p. 122 -- 5.3 p. 123 -- 5.4 p. 124 -- 5.4.1 p. 124 -- 5.4.2 p. 124 -- 5.4.3 p. 126 -- 5.4.4 p. 130 -- 5.4.5 p. 131 -- 5.4.5.1 p. 132 -- 5.4.5.2 p. 135 -- 6 p. 145 / 6.2 p. 146 -- 6.2.1 p. 147 -- 6.2.2 p. 148 -- 6.2.3 p. 148 -- 6.2.3 p. 150 -- 6.3 p. 150 -- 6.4 p. 151 -- 6.4.1 p. 151 -- 6.4.2 p. 152 -- 6.4.3 p. 153 -- 6.4.4 p. 154 -- 6.5 p. 154 -- 6.6 p. 156 -- 6.7 p. 158 -- 6.7.1 p. 158 -- 6.7.2 p. 159 -- 6.7.3 p. 160 -- 6.7.4 p. 161 -- 6.7.5 p. 162 -- 6.7.6 p. 162 -- 6.8 p. 163 -- Part II p. 175 -- 7 p. 177 / 7.2 p. 179 -- 7.3 p. 182 -- 7.4 p. 184 -- 7.5 p. 185 -- 7.6 p. 187 -- 7.7 p. 188 -- 7.8 p. 189 -- 8 p. 197 / 8.2 p. 198 -- 8.3 p. 200 -- 8.3.1 p. 200 -- 8.3.2 p. 202 -- 8.3.3 p. 204 -- 8.3.4 p. 206 -- 8.4 p. 207 -- 8.5 p. 208 -- 8.6 p. 210 -- 8.7 p. 217 -- 9 p. 225 -- 9.2 p. 225 -- 9.3 p. 227 -- 9.4 p. 230 -- 9.5 p. 234 -- 9.6 p. 236 -- 10 p. 249 / 10.2 p. 250 -- 10.2.1 p. 250 -- 10.2.2 p. 253 -- 10.3 p. 258 -- 10.3.1 p. 258 -- 10.3.2 p. 260 -- 10.3.3 p. 263 -- 10.3.4 p. 268 -- 10.3.5 p. 271 -- Part III p. 279 -- 11 p. 281 / 11.2 p. 282 -- 11.2.1 p. 282 -- 11.2.2 p. 284 -- 11.2.3 p. 286 -- 11.3 p. 286 -- 11.3.1 p. 287 -- 11.3.2 p. 288 Elastin-functionalised Metallic Nanoparticles Other Polymer-functionalised Metallic Nanoparticles Magnetic Nanoparticles pNIPAM-functionalised Magnetic Nanoparticles Poloxamer-functionalised Magnetic Nanoparticles Other TRP-functionalised Magnetic Nanoparticles Temperature-responsive Polymers for Tissue Engineering Thermo-responsive Cell Culture Dishes and Cell Sheets Thermo-responsive Cell Culture Dishes Prepared by Electron-beam-induced Polymerization Thermo-responsive Cell Culture Dishes for Enhancing Cell Adhesion and Proliferation by Immobilized Biological Ligands Thermo-responsive Cell Culture Dish Prepared by Living Radical Polymerization Patterned Thermo-responsive Cell Culture Substrates Thermo-responsive Surfaces for Cell Separation Thermogel Polymers for Injectable Drug Delivery Systems Pluronics® Polyester-based Polymers Chitosan and Derivatives Polypeptides Clinical Application of Thermogel Polymers Ocular Delivery Nasal Delivery Antitumor Delivery/Drug Delivery Systems Thermoresponsive Electrospun Polymer-based (Nano)fibers Basic Principles of Electrospinning PNIPAM-based Electrospun (Nano)fibers Temperature-triggered Wettability Biomedicine Drug Delivery Tissue Engineering Biosensing Solid-phase Microextraction Molecular Recognition Organic-Inorganic PNIPAM-based Electrospun (Nano)fibers Sensing Other Types of Thermoresponsive Electrospun (Nano)fibers Catalysis by Thermoresponsive Polymers Metal Complexes Immobilized Within Thermosensitive Polymers Thermoresponsive Polyampholytes Thermosensitive Hydrogels in Catalysis Thermoresponsive Catalytically Active Nano- and Microgels, Spheres, Capsules, and Micelles Thermosensitive Self-Assemblies Mono- and Bimetallic Nanoparticles Stabilized by Thermoresponsive Polymers Enzymes-Embedded Thermoresponsive Polymers Immobilization of Magnetic Nanoparticles into the Matrix of Thermoresponsive Polymers for Efficient Separation of Catalysts Kenichi Nagase and Masayuki Yamato and Teruo Okano -- Vidhi M. Shah and Duc X. Nguyen and Deepa A. Rao and Raid G. Alany and Adam W.G. Alani -- Mariliz Achilleos and Theodora Krasia-Christoforou -- Natalya A. Dolya and Sarkyt E. Kudaibergenov -- 11.3.3 p. 288 -- 11.3.4 p. 289 -- 11.4 p. 290 -- 11.4.1 p. 290 -- 11.4.2 p. 291 -- 11.4.3 p. 293 -- 12 p. 301 / 12.1.1 p. 301 -- 12.1.2 p. 302 -- 12.1.3 p. 303 -- 12.1.4 p. 304 -- 12.1.5 p. 306 -- 12.1.6 p. 309 -- 13 p. 313 / 13.2 p. 314 -- 13.3 p. 315 -- 13.4 p. 317 -- 13.5 p. 318 -- 13.6 p. 319 -- 13.6.1 p. 319 -- 13.6.2 p. 320 -- 13.6.3 p. 321 -- 14 p. 329 / 14.2 p. 330 -- 14.3 p. 332 -- 14.3.1 p. 332 -- 14.3.2 p. 335 -- 14.3.2.1 p. 336 -- 14.3.2.2 p. 339 -- 14.3.2.3 p. 341 -- 14.3.2.4 p. 341 -- 14.3.2.5 p. 342 -- 14.3.2.6 p. 342 -- 14.3.3 p. 343 -- 14.4 p. 345 -- 15 p. 357 / 15.2 p. 358 -- 15.3 p. 358 -- 15.4 p. 361 -- 15.5 p. 364 -- 15.6 p. 367 -- 15.7 p. 368 -- 15.8 p. 369 -- 15.9 p. 369.